You asked:

Is Polymyxin B the same as Neosporin?

No
Neosporin
Neosporin

Neosporin (from Neo, (Greek) new + Sporos, (Greek) seed), the product name of an antibiotic ointment produced by Pfizer (later sold to Johnson & Johnson) used in the prevention of infection and speeding the healing of wounds

Polymyxin B
Polymyxin B

Polymyxin B, the antibiotic primarily used for resistant gram-negative infections

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